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In physics, wave-particle duality holds that light and matter simultaneously exhibit properties of waves and of particles (or photons). This concept is a consequence of quantum mechanics.
Fresnel, Maxwell, and Young
In the early 1800s, the double-slit experiments by Young and Fresnel provided
evidence for Huygens' theories: these experiments showed that when light is sent through a grid, a characteristic interference pattern is observed, very similar to the pattern
resulting from the interference of water waves; the wavelength of light can be computed from such patterns. Maxwell, during the late-1800s, explained light as the
propagation of electromagnetic waves with the Maxwell equations. These equations were verified by experiment, and
Huygens' view became widely accepted.
Einstein and photons
In 1905, Einstein reconciled
Huygens' view with that of Newton; he explained the photoelectric effect (an effect in which light did not seem to act
as a wave) by postulating the existence of photons, quanta of energy with particulate
qualities. Einstein postulated that light's
frequency, ν, is related to the energy, E, of its photons:
- E = hν,
where h is Planck's constant (6.626 x
10-34 J seconds).
De Broglie
In 1924, De
Broglie claimed that all matter has a wave-like nature; he related wavelength, λ, and momentum, p:
- .
This is a generalization of Einstein's equation above since the momentum of a
photon is given by p = E / c where c is the speed of light in vacuum, and λ =
c / ν.
De Broglie's formula was confirmed three years later by guiding a beam of electrons (which have rest mass) through a crystalline grid and observing the predicted interference patterns.
Similar experiments have since been conducted with neutrons and protons. Authors of similar recent experiments with atoms and
molecules claim that these larger particles also act like waves. This is still a contoversial subject because these experimenters
have assumed arguments of wave-particle duality and have assumed the validity of deBroglie's equation in their argument.
The Planck constant h is extremely small and that explains why we don't perceive a wave-like quality of everyday
objects: their wavelengths are exceedingly small. The fact that matter can have very short wavelengths is exploited in electron microscopy.
In quantum mechanics, the wave-particle duality is explained
as follows: every system and particle is described by state functions which encode the probability distributions of all
measurable variables. The position of the particle is one such variable. Before an observation is made the position of the
particle is described in terms of probability waves which can interfere with each other.
An intriguingly simple experiment, the double-slit
experiment, summarizes the duality: aim an electron gun at a screen with two slits and record their positions of detection at
a detector behind the screen. You will observe an interference pattern just like the one produced by diffraction of a light or
water wave at two slits. This pattern will even appear if you slow down the electron source so that only one electron's worth of
charge per second comes through. "Classically speaking", every electron is a point particle and must either travel through the
first or through the second slit. So we should be able to produce the same interference pattern if we ran the experiment twice as
long, closing slit number one for the first half, then closing slit number two for the second half. But the same pattern does not
emerge. Furthermore, if we build detectors around the slits in order to determine which path a particular electron takes, this
very measurement destroys the interference pattern as well. But this is a classical explanation and something much more profound
is taking place.
The interference pattern is a result of the charge wave being diffracted by both slits and interfering with itself.
In quantum mechanics, the state function is a complex valued function of space and time. The square of the magnitude of this function describes the probability of finding the electron at a given location at
a given time. Interference is due to the fact that the square of the magnitude of the sum of two complex numbers may be different from the sum of the squares of their magnitudes.
The experiment also illustrates an interesting feature of quantum mechanics. Until an observation is made the position of a
particle is described in terms of probability waves, but after the particle is observed, it is described as a fixed value. How to
conceptualize the process of measurement is one of the great unresolved questions of quantum mechanics. The standard
interpretation is the Copenhagen interpretation
which leads to interesting thought experiments such as Schrödinger's cat. There is so much confusion over wave-particle
duality that theorists have become desperate enough to consider such things as the many-worlds interpretation.
See also
- Quantum Mechanics, X-rays, Photoelectric effect, Diffraction, electromagnetism, electron, Erwin Schrödinger, Max
Planck, Albert Einstein, Niels Bohr, Louis de Broglie, double-slit experiment
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